Product ID:UNLEADED 87-7.8 RVP
MSDS Date:04/30/1992
FSC:9130
NIIN:00-148-7104
MSDS Number: BRFLY

CITGO PETROLEUM CORP

6100 S YALE BLDG 1 WARREN PL
TULSA, OK 74102
US

Emergency Phone: 318-491-6215/800-424-9300(CHEMTREC)

Info Phone: 918-495-5933

Cage: 7X110

CITGO PETROLEUM CORP

3758 TULSA, OK 74102 US

Telephone: 918-495-5933

Cage: 7X110

PETROLEUM DISTILLATES (CONTAINS INGREDIENTS 4, 5, 6 ...)

Fraction By Weight: 85 - 98%

OSHA PEL 5 MG/M3 AS OIL MIST

ACGIH TLV: 5 MG/M3 AS OIL MIST

LOWER ALIPHATIC ALCOHOLS

Fraction By Weight: 0 - 11%

LOWER ALIPHATIC ETHERS

Fraction By Weight: 0 - 15%

BENZENE (SARA III), 0-5%

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: SEE # 1%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9293

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

TERT-BUTYL ALCOHOL (SARA III), 0-10%

CAS: 75-65-0

RTECS: EO1925000

Fraction By Weight: SEE # 1%

OSHA PEL 100 PPM

ACGIH TLV: 100PPM 9394

ETHYL BENZENE (SARA III), 0-5%

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: SEE # 1%

OSHA PEL 100 PPM/125 STEL

ACGIH TLV: 100 PPM/125STEL 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHYL TERT-BUTYL ETHER (SARA III), 0-15%

CAS: 1634-04-4

RTECS: KN5250000

Fraction By Weight: SEE # 1%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

TOLUENE (SARA III), 0-25%

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: SEE # 1%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1,2,4-TRIMETHYLBENZENE (SARA III), 0-5%

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: SEE # 1%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9293

XYLENES (O-,M-,P- ISOMERS) (SARA III), 0-25%

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: SEE # 1%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:TLV FOR BENZENE IS 10 PPM.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE- INHALATION OF VAPORS MAY CAUSE
CNS DEPRESSION, CONVULSION, LOSS OF CONSCIOUSNESS. INGESTION HAS
SYMPTOMS SIMILAR TO INHALATION & ASPIRATION HAZARD. EYE/SKIN
CONTACT CAUSES IRRITATION. CHRONIC- DERMATITIS, NERVOUS SYSTEM,
KIDNEY, LIVER & BLOOD DISORDERS INCLUDING ANEMIA & LEUKEMIA. KIDNEY
CANCER IN LAB ANIMALS.
Explanation of Carcinogenicity:CONTAINS BENZENE. MAY CAUSE BLOOD
DISEASES INCLUDING LEUKEMIA. VAPORS MAY CAUSE KIDNEY CANCER IN MALE
RATS.
Effects of Overexposure:HEADACHE, NASAL & RESPIRATORY IRRITATION,
NAUSEA, DROWSINESS, FATIGUE, EYE & SKIN IRRITATION, PULMONARY
EDEMA, CONVULSION & LOSS OF CONSCIOUSNESS
Medical Cond Aggravated by Exposure:BENZENE- INDIVIDUALS WITH LIVER,
KIDNEY AND BLOOD DISEASES. HEXANE- INDIVIDUALS WITH NEUROLOGICAL
DISEASES. PETROLEUM SOLVENT- THOSE WITH EXISTING DERMATITIS.

First Aid:CALL A PHYSICIAN IN ALL CASES. EYES:IMMEDIATELY FLUSH WITH
WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP &
WATER. INHALED:REMOVE TO FRESH AIR & PROVIDE CPR/OXYGEN IF
NECESSARY. ORAL: DO NOT INDUCE VOMITING. DO NOT DRINK LIQUIDS.
OBTAIN EMERGENCY MEDICAL ATTENTION. SMALL AMOUNTS WHICH
ACCIDENTALLY ENTER MOUTH SHOULD BE RINSED OUT UNTIL TASTE OF IT IS
GONE.

Flash Point Method:COC
Flash Point:-45F,-43C
Lower Limits:1.4
Upper Limits:7.6
Extinguishing Media:USE CARBON DIOXIDE, FOAM, DRY CHEMICAL AND
VAPORIZING LIQUID TYPE EXTINGUISHERS. WATER MAY BE INEFFECTIVE.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT & A
FULL FACED SELF CONTAINED BREATHING APPARATUS/SUPPLIED-AIR
RESPIRATOR.COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:THE INVISIBLE VAPORS ARE HEAVIER THAN AIR
AND TRAVEL SOME DISTANCE TO IGNITION SOURCES & FLASH BACK. CAN FORM
FLAMMABLE MIXTURE WITH AIR & FLASH AT ROOM TEMP.

Spill Release Procedures:WEAR PROTECTIVE EQUIPMENTS.ELIMINATE ALL
SOURCES OF IGNITION.USE EXPLOSION-PROOF TOOLS.SHUT OFF FUEL
SOURCE.DIKE SPILL.PREVENT LIQUID FROM ENTERING
SEWERS/WATERWAYS.RECOVER FREE LIQUID.ADD SAND,EARTH OR OTHER
ABSORBENT MATERIAL.TRANSFER TOCONTAINER.

Handling and Storage Precautions:STORE IN ACCORDANCE WITH NATIONAL FIRE
PROTECTION ASSOCIATION REGULATIONS. KEEP CONTAINERS CLOSED.
Other Precautions:"EMPTY" CONTAINERS RETAIN RESIDUE AND CAN BE
DANGEROUS. DO NOT PRESSURIZE, CUT, WELD, SOLDER, DRILL OR EXPOSE
SUCH CONTAINERS TO HEAT, FLAME, SPARKS. THEY MAY EXPLODE AND CAUSE
INJURY/DEATH. AVOID REP EATED OR PROLONGED CONTACT WITH SKIN.

Respiratory Protection:NIOSH-APPROVED SELF-CONTAINED BREATHING
APPARATUS OR ORGANIC VAPOR RESPIRATOR OR SUPPLIED-AIR RESPIRATOR,
IF NEEDED.
Ventilation:LOCAL/MECHANICAL (GENERAL) VENTILATION - EXPLOSION PROOF,
WELL GROUNDED EQUIPMENTS
Protective Gloves:RUBBER RECOMMENDED
Eye Protection:CHEMICAL SPLASH GOGGLES & FACE SHIELD
Other Protective Equipment:IMPERVIOUS CLOTHING TO AVOID SKIN AND EYE
CONTACT. EYE WASH STATION & SAFETY SHOWER.
Work Hygienic Practices:AVOID CONTACT WITH EYES, SKIN OR CLOTHING. WASH
HANDS AFTER USING PRODUCT. AVOID BREATHING VAPORS OR MISTS.
Supplemental Safety and Health
FORMULA CHANGED. FOR PREVIOUS FORMULATION, SEE PNI A UNDER THE SAME
NSN.

HCC:F1
Boiling Pt:B.P. Text:95.0F,35.0C
Melt/Freeze Pt:M.P/F.P Text:NOT KNOWN
Vapor Pres:510-760
Vapor Density:3 - 4
Spec Gravity:0.75
Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:LIGHT YELLOW OR CLEAR LIQUID - GASOLINE ODOR
Percent Volatiles by Volume:HIGH

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS, STRONG BASES
Stability Condition to Avoid:HIGH HEAT, SPARKS, OPEN FLAMES AND OTHER
SOURCES OF IGNITION
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND
OTHER DECOMPOSITION PRODUCTS

Waste Disposal Methods:RECYCLE AS MUCH AS POSSIBLE. TREATMENT, STORAGE,
TRANSPORTATION AND DISPOSAL MUST BE IN ACCORDANCE WITH ALL
APPLICABLE LOCAL, STATE AND FEDERAL LAWS AND REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.